Visual Studio 2010 and .NET Framework 4.0 Training Kit
The Visual Studio 2010 and .NET Framework 4.0 Training Kit includes presentations, hands-on labs, and demos. This content is designed to help you learn how to utilize the Visual Studio 2010 features and a variety of framework technologies including: C# 4.0, Visual Basic 10, F#, Parallel Computing Platform, WCF, WF, WPF, ASP.NET AJAX 4.0, ASP.NET MVC Dynamic Data
You will also need to download the VPC of VS 2010 and .NET 4.0 from here
And if you want to learn about Azure check out the Azure Services Training Kit from here