Holy smokes, it finally happened - VS2005 on MSDN Subscriber Downloads
Unfortunately, I'm just getting errors when I try to download it right now.
Update - It seems that which media you see depends on which server you hit. I went back in again, and the CD version was gone and the DVD version was there. I was able to successfully kick off a DVD download, and it's chugging along. Should be done downloading sometime next month. ;)